{2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC 1}iodidobis(trimethyl­phos­phane)cobalt(II)

نویسندگان

  • Jiong Jia
  • Chenggen Wang
  • Nazhen Liu
  • Xiaoyan Li
چکیده

In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co-C-C-C-P ring.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC 1]bis­(tri­methyl­phosphine-κP)cobalt(III)

In the title compound, [Co(C(7)F(7))Cl(2)(C(3)H(9)P)(2)], the Co(III) atom displays a trigonal-bipyramidal coordination geometry, with the two Cl ligands and the C atom of the perfluoro-tolyl ligand in the equatorial plane and the two phosphine ligands occupying axial positions. The mol-ecule has an approximate C(2v) symmetry. The trifluoro-methyl group is disordered over two positions, with ne...

متن کامل

{1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC 2}iodido(trimethyl­phosphane)cobalt(II)

The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo-butane to a solution of the parent cobalt complex {1,3-bis-[(diphenyl-phosphan-yl)-oxy]prop-2-yl}bis-(trimethyl-phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter-nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and...

متن کامل

rac-cis-Dicarbonyl­chlorido{1-[2-(diphenyl­phosphanyl-κP)benz­yl]-3-(phenyl-κC 1)imidazol-2-yl­idene-κC 2}ruthenium(II) dichloro­methane monosolvate

In the title compound, [Ru(C(28)H(22)N(2)P)Cl(CO)(2)]·CH(2)Cl(2), the Ru(II) atom exhibits a distorted octa-hedral coordination geometry. The N-phenyl group of the ligand has undergone orthometalation; as a result, the tridentate phosphane-functionalized N-heterocyclic carbene ligand is coordinating in a meridional fashion. This complex is of inter-est with respect to transfer hydrogenation cat...

متن کامل

cis-Dichlorido(3-chloro-2-methyl­imino­phenyl-κ2 C 1,N)-trans-bis­(trimethyl­phosphine-κP)cobalt(III)

In the title compound, [CoCl(2)(C(8)H(7)ClN)(C(3)H(9)P)(2)], the Co atom displays an octa-hedral coordination, with two cis Cl atoms perpendicular to two trans trimethyl-phosphine ligands as well as trans to the bidentate 3-chloro-2-methyl-imino-phenyl ligand.

متن کامل

Crystal structures of di­iodido­bis­[(1S,5S)-4-mesityl-1,2,8,8-tetra­methyl-2,4-di­aza­bicyclo­[3.2.1]octan-3-yl­idene-κC 3]palladium(IV) and di­chlorido­[(1S,5S)-4-mesityl-1,2,8,8-tetra­methyl-2,4-di­aza­bicyclo[3.2.1]octan-3-yl­idene-κC 3](tri­phenyl­phosphane-κP)palladium(IV)

The mol-ecular structures of the chiral title compounds, [Pd(C19H28N2)2I2], (I), and [Pd(C19H28N2)Cl2(C18H15P)], (II), show a distorted square-planar coordination around the Pd(II) atoms with two halogenide (Hal) ligands each and two N-heterocyclic carbene (NHC) ligands in (I) or one NHC and one tri-phenyl-phosphane ligand in (II). The deviations of the Pd(II) atoms from the L 2Hal2 best plane ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011